Zhao Jing was born in 736, during the reign of Emperor Xuanzong. His family was from Wei Prefecture. and traced its origins to the royal house of the Warring States period state Zhao. His great-grandfather Zhao Renben served as a chancellor during the reign of Emperor Xuanzong's grandfather Emperor Gaozong, and his grandfather Zhao Yi and father Zhao Daoxian both served in government as well. Zhao Jing himself was said to be studious, and in his youth behaved well and did not seek prominence.
During Emperor Daizong's reign
In 762, after Emperor Xuanzong's grandson Emperor Daizong had just taken the throne after both Emperor Xuanzong and Emperor Daizong's father Emperor Suzong died earlier that year, the officials in charge of the emperors' funerals were discussing how the two emperors should be buried. Zhao Jing, then a commoner, submitted a petition arguing that, as there was a famine at the time and Tufan incursions, the funerals should be done in a frugal manner. He was praised by others for this petition. As a result, he later served as an official at a prefectural government, then the acting sheriff of Jiangxia County, and yet later successively served as an imperial censor first under the title of Jiancha Yushi then Dianzhong Shiyushi ; and Taizi Sheren, a member of the staff of Emperor Daizong's crown princeLi Kuo. When his mother died, he left governmental service to observe a period of mourning for her.
During Emperor Dezong's reign
In 779, Emperor Daizong died, and Li Kuo became emperor. Early in Emperor Dezong's Jianzhong era, with Zhao Jing's mourning period over, he was recalled to the imperial government to serve at Shuibu Yuanwailang, a low-level officer at the ministry of public works. However, before he could take office, Li Cheng the governor of Hunan Circuit requested Zhao to serve as his deputy. After a year, Li Cheng died, and for some time Zhao served as acting governor. He was soon made the prefect of Hunan's capital Tan Prefecture and governor of Hunan. He was governor for two years before he was replaced, and after he returned to the capital Chang'an, he stayed at home and had no association with others. A long time thereafter, Emperor Dezong summoned him to the palace to meet him. As Zhao was well-learned and good at speaking, Emperor Dezong was pleased to meet him and made him an imperial attendant. In 788, Huige's Heguduolu Khan Yaoluoge Dunmohe requested to marry a Tang princess, and Emperor Dezong agreed to give Yaoluoge Dunmohe his daughter Princess Xian'an in marriage. The senior official Guan Bo was commissioned to serve as her escort, and Zhao served as Guan's deputy. At that time, Tang emissaries to Huige often used the opportunity to conduct commercial transactions for their own benefit as well, but Zhao did not do so, and people were impressed with him. After he returned from the mission, he became Shangshu Zuo Cheng, one of the secretaries general of the executive bureau of government. It was said that he oversaw the bureau business with diligence and integrity. At that time, Dou Can was the primary chancellor and disliked Zhao for his abilities, viewing him as a threat. He requested that Zhao be made the prefect of Tong Prefecture, but Emperor Dezong refused. In 792, Dou was demoted and exiled, and Lu Zhi and Zhao were made chancellors with the designationTong Zhongshu Menxia Pingzhangshi. Both of them were also made Zhongshu Shilang, the deputy head of the legislative bureau. As chancellor, Zhao drafted a major six-part policy proposal with regard to the commissioning of officials:
That, as far as commissioning chancellors are concerned, Emperor Dezong should seek people who are capable, and not be concerned about them being perfect.
That the ranks of the officials should be increased, such that more talented people could be found for governmental service.
That the officials at the capital were being overworked and needed additional help to share their work.
That further effort be made to promote or demote officials in accordance with their performance.
That additional peer evaluations be done on officials, so that people with good performance would not be hidden from view.
That talented staff members of regional governors should be promoted to the imperial government.
However, as Emperor Dezong trusted Lu more, Lu was given more of the responsibilities. In 793, Zhao was made Menxia Shilang, the deputy head of the examination bureau instead of Zhongshu Shilang, although he remained as chancellor. As the office of the chancellors was then inside the legislative bureau, Zhao suspected Lu of wanting to force him out of the key decision-making, and he resented Lu for this. Zhao thereafter often claimed to be ill in his eye and did not attend to the main policy decisions. Still, Zhao was credited for protecting such officials as Du Huangchang, Mu Zan, Wei Wu, Li Xuan, and Lu Yun from suffering from false accusations. He was also credited with promoting former subordinates Linghu Heng and Cui Jing despite their prior attempts to undermine him. Meanwhile, despite Lu Zhi's repeatedly criticizing the official Pei Yanling as frivolous and deceitful, Emperor Dezong trusted Pei and repeatedly promoted him. Lu, not knowing that Zhao resented him with regard to Zhao's move to the examination bureau, often criticized Pei while meeting with Zhao, and Zhao leaked Lu's criticism to Pei, allowing Pei to deflect the criticism when meeting with Emperor Dezong and further strike back at Lu. On an occasion when Lu arranged to meet Emperor Dezong with Zhao, with the purpose of criticizing Pei together, Emperor Dezong became displeased when Lu did so, and Zhao watched and said nothing. Around new year 795, Lu was removed from his chancellor position, and Zhao became the main chancellor. In spring 796, on an occasion when his chancellor colleagues Jia Dan and Lu Mai were on vacation, Zhao met with Emperor Dezong alone, and on that occasion advocated the restoration of an early Tang institution — that subordinate officials be around to record the events at the meetings between the emperor and the chancellors. Emperor Dezong agreed, but as Zhao died shortly thereafter, in fall 796, the institution was not restored. Emperor Dezong mourned Zhao greatly and gave him the posthumous name Zhenxian.