Corrosion in space has the highest impact on spacecraft with moving parts. Early satellites tended to develop problems with seizing bearings. Now the bearings are coated with a thin layer of gold. Different materials resist corrosion in space differently. For example, aluminium is slowly eroded by atomic oxygen, while gold and platinum are highly corrosion-resistant. Gold-coated foils and thin layers of gold on exposed surfaces are therefore used to protect the spacecraft from the harsh environment. Thin layers of silicon dioxide deposited on the surfaces can also protect metals from the effects of atomic oxygen; e.g., the Starshine 3 satellite aluminium front mirrors were protected that way. However, the protective layers are subject to erosion by micrometeorites. Silver builds up a layer of silver oxide, which tends to flake off and has no protective function; such gradual erosion of silver interconnects of solar cells was found to be the cause of some observed in-orbit failures. Many plastics are considerably sensitive to atomic oxygen and ionizing radiation. Coatings resistant to atomic oxygen are a common protection method, especially for plastics. Silicone-based paints and coatings are frequently employed, due to their excellent resistance to radiation and atomic oxygen. However, the silicone durability is somewhat limited, as the surface exposed to atomic oxygen is converted to silica which is brittle and tends to crack.
Solving corrosion
The process of space corrosion is being actively investigated. One of the efforts aims to design a sensor based on zinc oxide, able to measure the amount of atomic oxygen in the vicinity of the spacecraft; the sensor relies on drop of electrical conductivity of zinc oxide as it absorbs further oxygen.
Other problems
The outgassing of volatile silicones on low Earth orbit devices leads to presence of a cloud of contaminants around the spacecraft. Together with atomic oxygen bombardment, this may lead to gradual deposition of thin layers of carbon-containing silicon dioxide. Their poor transparency is a concern in case of optical systems and solar panels. Deposits of up to several micrometers were observed after 10 years of service on the solar panels of the Mir space station. Other sources of problems for structures subjected to outer space are erosion and redeposition of the materials by sputtering caused by fast atoms and micrometeoroids. Another major concern, though of non-corrosive kind, is material fatigue caused by cyclical heating and cooling and associated thermal expansion mechanical stresses.
